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The forecast model in the version (CY41R2) of the ECMWF Integrated Forecasting System (IFS) used in ERA5, has a cold bias in the lower regions of the troposphere over most parts over the globe, which is at least partially corrected by the analysis system. This forecast cold bias means that the analysed "2 metre temperature" can be larger than the "Maximum temperature at 2 metres since previous post-processing".
Given this inconsistency in these three parameters on the CDS, we recommend in general that the hourly "2 metre temperature" be used to construct the minimum and maximum over longer periods, such as a day. However, be aware that with the "2 metre temperature" being an instantaneous parameter, it is given by the time step value on the hour, whereas the "Maximum temperature at 2 metres since previous post-processing" and "Minimum temperature at 2 metres since previous post-processing" are calculated from all the time steps during the hour. In ERA5, the time step is 12 minutes, so there are five time steps per hour.
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