Remember that you can use the dynamic ECMWF Public Dataset web interface to discover the available data:
In the following link you can find documentation and examples of S2S retrievals. You have to select the centre that provide the data and then you will be able to find the Python request:
This is the list of different Python examples:
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BoM re-forecast examples (S2S)
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BoM real-time examples (S2S)
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ECMWF real-time examples (S2S)
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JMA re-forecast examples (S2S)
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JMA real-time examples (S2S)
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NCEP real-time examples (S2S)